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By NASA
3 min read
Preparations for Next Moonwalk Simulations Underway (and Underwater)
NASA’s Curiosity Mars rover sees its tracks receding into the distance at a site nicknamed “Ubajara” on April 30, 2023. This site is where Curiosity made the discovery of siderite, a mineral that may help explain the fate of the planet’s thicker ancient atmosphere.Credit: NASA/JPL-Caltech/MSSS New findings from NASA’s Curiosity Mars rover could provide an answer to the mystery of what happened to the planet’s ancient atmosphere and how Mars has evolved over time.
Researchers have long believed that Mars once had a thick, carbon dioxide-rich atmosphere and liquid water on the planet’s surface. That carbon dioxide and water should have reacted with Martian rocks to create carbonate minerals. Until now, though, rover missions and near-infrared spectroscopy analysis from Mars-orbiting satellites haven’t found the amounts of carbonate on the planet’s surface predicted by this theory.
Reported in an April paper in Science, data from three of Curiosity’s drill sites revealed the presence of siderite, an iron carbonate mineral, within the sulfate-rich rocky layers of Mount Sharp in Mars’ Gale Crater.
“The discovery of abundant siderite in Gale Crater represents both a surprising and important breakthrough in our understanding of the geologic and atmospheric evolution of Mars,” said Benjamin Tutolo, associate professor at the University of Calgary, Canada, and lead author of the paper.
To study the Red Planet’s chemical and mineral makeup, Curiosity drills three to four centimeters down into the subsurface, then drops the powdered rock samples into its CheMin instrument. The instrument, led by NASA’s Ames Research Center in California’s Silicon Valley, uses X-ray diffraction to analyze rocks and soil. CheMin’s data was processed and analyzed by scientists at the Astromaterials Research and Exploration Science (ARES) Division at NASA’s Johnson Space Center in Houston.
“Drilling through the layered Martian surface is like going through a history book,” said Thomas Bristow, research scientist at NASA Ames and coauthor of the paper. “Just a few centimeters down gives us a good idea of the minerals that formed at or close to the surface around 3.5 billion years ago.”
The discovery of this carbonate mineral in rocks beneath the surface suggests that carbonate may be masked by other minerals in near-infrared satellite analysis. If other sulfate-rich layers across Mars also contain carbonates, the amount of stored carbon dioxide would be a fraction of that needed in the ancient atmosphere to create conditions warm enough to support liquid water. The rest could be hidden in other deposits or have been lost to space over time.
In the future, missions or analyses of other sulfate-rich areas on Mars could confirm these findings and help us better understand the planet’s early history and how it transformed as its atmosphere was lost.
Curiosity, part of NASA’s Mars Exploration Program (MEP) portfolio, was built by NASA’s Jet Propulsion Laboratory, which is managed by Caltech in Pasadena, California. JPL leads the mission on behalf of NASA’s Science Mission Directorate in Washington.
For more information on Curiosity, visit:
https://science.nasa.gov/mission/msl-curiosity
News Media Contacts
Karen Fox / Molly Wasser
NASA Headquarters, Washington
202-358-1600
karen.c.fox@nasa.gov / molly.l.wasser@nasa.gov
Andrew Good
Jet Propulsion Laboratory, Pasadena, Calif.
818-393-2433
andrew.c.good@jpl.nasa.gov
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Last Updated Apr 17, 2025 Related Terms
Ames Research Center Astromaterials Curiosity (Rover) General Jet Propulsion Laboratory Mars Science Laboratory (MSL) Explore More
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Mars is the fourth planet from the Sun, and the seventh largest. It’s the only planet we know of inhabited…
Curiosity Science Instruments
Curiosity’s scientific instruments are the tools that bring us stunning images of Mars and ground-breaking discoveries.
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By European Space Agency
The European Space Agency's XMM-Newton is playing a crucial role in investigating the longest and most energetic bursts of X-rays seen from a newly awakened black hole. Watching this strange behaviour unfold in real time offers a unique opportunity to learn more about these powerful events and the mysterious behaviour of massive black holes.
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By European Space Agency
Video: 00:05:23 For over a decade, ESA’s Gaia mission has mapped our galaxy with stunning precision—rewriting the story of the Milky Way. As its mission enters a new phase, we look back at its most groundbreaking discoveries.
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By European Space Agency
The European Space Agency (ESA) has powered down its Gaia spacecraft after more than a decade spent gathering data that are now being used to unravel the secrets of our home galaxy.
On 27 March 2025, Gaia’s control team at ESA’s European Space Operations Centre carefully switched off the spacecraft’s subsystems and sent it into a ‘retirement orbit’ around the Sun.
Though the spacecraft’s operations are now over, the scientific exploitation of Gaia’s data has just begun.
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By NASA
Researchers analyzing pulverized rock onboard NASA’s Curiosity rover have found the largest organic compounds on the Red Planet to date. The finding, published Monday in the Proceedings of the National Academy of Sciences, suggests prebiotic chemistry may have advanced further on Mars than previously observed.
Scientists probed an existing rock sample inside Curiosity’s Sample Analysis at Mars (SAM) mini-lab and found the molecules decane, undecane, and dodecane. These compounds, which are made up of 10, 11, and 12 carbons, respectively, are thought to be the fragments of fatty acids that were preserved in the sample. Fatty acids are among the organic molecules that on Earth are chemical building blocks of life.
Living things produce fatty acids to help form cell membranes and perform various other functions. But fatty acids also can be made without life, through chemical reactions triggered by various geological processes, including the interaction of water with minerals in hydrothermal vents.
While there’s no way to confirm the source of the molecules identified, finding them at all is exciting for Curiosity’s science team for a couple of reasons.
Curiosity scientists had previously discovered small, simple organic molecules on Mars, but finding these larger compounds provides the first evidence that organic chemistry advanced toward the kind of complexity required for an origin of life on Mars.
This graphic shows the long-chain organic molecules decane, undecane, and dodecane. These are the largest organic molecules discovered on Mars to date. They were detected in a drilled rock sample called “Cumberland” that was analyzed by the Sample Analysis at Mars lab inside the belly of NASA’s Curiosity rover. The rover, whose selfie is on the right side of the image, has been exploring Gale Crater since 2012. An image of the Cumberland drill hole is faintly visible in the background of the molecule chains. NASA/Dan Gallagher The new study also increases the chances that large organic molecules that can be made only in the presence of life, known as “biosignatures,” could be preserved on Mars, allaying concerns that such compounds get destroyed after tens of millions of years of exposure to intense radiation and oxidation.
This finding bodes well for plans to bring samples from Mars to Earth to analyze them with the most sophisticated instruments available here, the scientists say.
“Our study proves that, even today, by analyzing Mars samples we could detect chemical signatures of past life, if it ever existed on Mars,” said Caroline Freissinet, the lead study author and research scientist at the French National Centre for Scientific Research in the Laboratory for Atmospheres and Space Observations in Guyancourt, France
In 2015, Freissinet co-led a team that, in a first, conclusively identified Martian organic molecules in the same sample that was used for the current study. Nicknamed “Cumberland,” the sample has been analyzed many times with SAM using different techniques.
NASA’s Curiosity rover drilled into this rock target, “Cumberland,” during the 279th Martian day, or sol, of the rover’s work on Mars (May 19, 2013) and collected a powdered sample of material from the rock’s interior. Curiosity used the Mars Hand Lens Imager camera on the rover’s arm to capture this view of the hole in Cumberland on the same sol as the hole was drilled. The diameter of the hole is about 0.6 inches. The depth of the hole is about 2.6 inches. NASA/JPL-Caltech/MSSS Curiosity drilled the Cumberland sample in May 2013 from an area in Mars’ Gale Crater called “Yellowknife Bay.” Scientists were so intrigued by Yellowknife Bay, which looked like an ancient lakebed, they sent the rover there before heading in the opposite direction to its primary destination of Mount Sharp, which rises from the floor of the crater.
The detour was worth it: Cumberland turns out to be jam-packed with tantalizing chemical clues to Gale Crater’s 3.7-billion-year past. Scientists have previously found the sample to be rich in clay minerals, which form in water. It has abundant sulfur, which can help preserve organic molecules. Cumberland also has lots of nitrates, which on Earth are essential to the health of plants and animals, and methane made with a type of carbon that on Earth is associated with biological processes.
Perhaps most important, scientists determined that Yellowknife Bay was indeed the site of an ancient lake, providing an environment that could concentrate organic molecules and preserve them in fine-grained sedimentary rock called mudstone.
“There is evidence that liquid water existed in Gale Crater for millions of years and probably much longer, which means there was enough time for life-forming chemistry to happen in these crater-lake environments on Mars,” said Daniel Glavin, senior scientist for sample return at NASA’s Goddard Space Flight Center in Greenbelt, Maryland, and a study co-author.
The recent organic compounds discovery was a side effect of an unrelated experiment to probe Cumberland for signs of amino acids, which are the building blocks of proteins. After heating the sample twice in SAM’s oven and then measuring the mass of the molecules released, the team saw no evidence of amino acids. But they noticed that the sample released small amounts of decane, undecane, and dodecane.
Because these compounds could have broken off from larger molecules during heating, scientists worked backward to figure out what structures they may have come from. They hypothesized these molecules were remnants of the fatty acids undecanoic acid, dodecanoic acid, and tridecanoic acid, respectively.
The scientists tested their prediction in the lab, mixing undecanoic acid into a Mars-like clay and conducting a SAM-like experiment. After being heated, the undecanoic acid released decane, as predicted. The researchers then referenced experiments already published by other scientists to show that the undecane could have broken off from dodecanoic acid and dodecane from tridecanoic acid.
The authors found an additional intriguing detail in their study related to the number of carbon atoms that make up the presumed fatty acids in the sample. The backbone of each fatty acid is a long, straight chain of 11 to 13 carbons, depending on the molecule. Notably, non-biological processes typically make shorter fatty acids, with less than 12 carbons.
It’s possible that the Cumberland sample has longer-chain fatty acids, the scientists say, but SAM is not optimized to detect longer chains.
Scientists say that, ultimately, there’s a limit to how much they can infer from molecule-hunting instruments that can be sent to Mars. “We are ready to take the next big step and bring Mars samples home to our labs to settle the debate about life on Mars,” said Glavin.
This research was funded by NASA’s Mars Exploration Program. Curiosity’s Mars Science Laboratory mission is led by NASA’s Jet Propulsion Laboratory in Southern California; JPL is managed by Caltech for NASA. SAM (Sample Analysis at Mars) was built and tested at NASA’s Goddard Space Flight Center in Greenbelt, Maryland. CNES (the French Space Agency) funded and provided the gas chromatograph subsystem on SAM. Charles Malespin is SAM’s principal investigator.
By Lonnie Shekhtman
NASA’s Goddard Space Flight Center, Greenbelt, Md.
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