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By NASA
Researchers analyzing pulverized rock onboard NASA’s Curiosity rover have found the largest organic compounds on the Red Planet to date. The finding, published Monday in the Proceedings of the National Academy of Sciences, suggests prebiotic chemistry may have advanced further on Mars than previously observed.
Scientists probed an existing rock sample inside Curiosity’s Sample Analysis at Mars (SAM) mini-lab and found the molecules decane, undecane, and dodecane. These compounds, which are made up of 10, 11, and 12 carbons, respectively, are thought to be the fragments of fatty acids that were preserved in the sample. Fatty acids are among the organic molecules that on Earth are chemical building blocks of life.
Living things produce fatty acids to help form cell membranes and perform various other functions. But fatty acids also can be made without life, through chemical reactions triggered by various geological processes, including the interaction of water with minerals in hydrothermal vents.
While there’s no way to confirm the source of the molecules identified, finding them at all is exciting for Curiosity’s science team for a couple of reasons.
Curiosity scientists had previously discovered small, simple organic molecules on Mars, but finding these larger compounds provides the first evidence that organic chemistry advanced toward the kind of complexity required for an origin of life on Mars.
This graphic shows the long-chain organic molecules decane, undecane, and dodecane. These are the largest organic molecules discovered on Mars to date. They were detected in a drilled rock sample called “Cumberland” that was analyzed by the Sample Analysis at Mars lab inside the belly of NASA’s Curiosity rover. The rover, whose selfie is on the right side of the image, has been exploring Gale Crater since 2012. An image of the Cumberland drill hole is faintly visible in the background of the molecule chains. NASA/Dan Gallagher The new study also increases the chances that large organic molecules that can be made only in the presence of life, known as “biosignatures,” could be preserved on Mars, allaying concerns that such compounds get destroyed after tens of millions of years of exposure to intense radiation and oxidation.
This finding bodes well for plans to bring samples from Mars to Earth to analyze them with the most sophisticated instruments available here, the scientists say.
“Our study proves that, even today, by analyzing Mars samples we could detect chemical signatures of past life, if it ever existed on Mars,” said Caroline Freissinet, the lead study author and research scientist at the French National Centre for Scientific Research in the Laboratory for Atmospheres and Space Observations in Guyancourt, France
In 2015, Freissinet co-led a team that, in a first, conclusively identified Martian organic molecules in the same sample that was used for the current study. Nicknamed “Cumberland,” the sample has been analyzed many times with SAM using different techniques.
NASA’s Curiosity rover drilled into this rock target, “Cumberland,” during the 279th Martian day, or sol, of the rover’s work on Mars (May 19, 2013) and collected a powdered sample of material from the rock’s interior. Curiosity used the Mars Hand Lens Imager camera on the rover’s arm to capture this view of the hole in Cumberland on the same sol as the hole was drilled. The diameter of the hole is about 0.6 inches. The depth of the hole is about 2.6 inches. NASA/JPL-Caltech/MSSS Curiosity drilled the Cumberland sample in May 2013 from an area in Mars’ Gale Crater called “Yellowknife Bay.” Scientists were so intrigued by Yellowknife Bay, which looked like an ancient lakebed, they sent the rover there before heading in the opposite direction to its primary destination of Mount Sharp, which rises from the floor of the crater.
The detour was worth it: Cumberland turns out to be jam-packed with tantalizing chemical clues to Gale Crater’s 3.7-billion-year past. Scientists have previously found the sample to be rich in clay minerals, which form in water. It has abundant sulfur, which can help preserve organic molecules. Cumberland also has lots of nitrates, which on Earth are essential to the health of plants and animals, and methane made with a type of carbon that on Earth is associated with biological processes.
Perhaps most important, scientists determined that Yellowknife Bay was indeed the site of an ancient lake, providing an environment that could concentrate organic molecules and preserve them in fine-grained sedimentary rock called mudstone.
“There is evidence that liquid water existed in Gale Crater for millions of years and probably much longer, which means there was enough time for life-forming chemistry to happen in these crater-lake environments on Mars,” said Daniel Glavin, senior scientist for sample return at NASA’s Goddard Space Flight Center in Greenbelt, Maryland, and a study co-author.
The recent organic compounds discovery was a side effect of an unrelated experiment to probe Cumberland for signs of amino acids, which are the building blocks of proteins. After heating the sample twice in SAM’s oven and then measuring the mass of the molecules released, the team saw no evidence of amino acids. But they noticed that the sample released small amounts of decane, undecane, and dodecane.
Because these compounds could have broken off from larger molecules during heating, scientists worked backward to figure out what structures they may have come from. They hypothesized these molecules were remnants of the fatty acids undecanoic acid, dodecanoic acid, and tridecanoic acid, respectively.
The scientists tested their prediction in the lab, mixing undecanoic acid into a Mars-like clay and conducting a SAM-like experiment. After being heated, the undecanoic acid released decane, as predicted. The researchers then referenced experiments already published by other scientists to show that the undecane could have broken off from dodecanoic acid and dodecane from tridecanoic acid.
The authors found an additional intriguing detail in their study related to the number of carbon atoms that make up the presumed fatty acids in the sample. The backbone of each fatty acid is a long, straight chain of 11 to 13 carbons, depending on the molecule. Notably, non-biological processes typically make shorter fatty acids, with less than 12 carbons.
It’s possible that the Cumberland sample has longer-chain fatty acids, the scientists say, but SAM is not optimized to detect longer chains.
Scientists say that, ultimately, there’s a limit to how much they can infer from molecule-hunting instruments that can be sent to Mars. “We are ready to take the next big step and bring Mars samples home to our labs to settle the debate about life on Mars,” said Glavin.
This research was funded by NASA’s Mars Exploration Program. Curiosity’s Mars Science Laboratory mission is led by NASA’s Jet Propulsion Laboratory in Southern California; JPL is managed by Caltech for NASA. SAM (Sample Analysis at Mars) was built and tested at NASA’s Goddard Space Flight Center in Greenbelt, Maryland. CNES (the French Space Agency) funded and provided the gas chromatograph subsystem on SAM. Charles Malespin is SAM’s principal investigator.
By Lonnie Shekhtman
NASA’s Goddard Space Flight Center, Greenbelt, Md.
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By NASA
4 min read
Preparations for Next Moonwalk Simulations Underway (and Underwater)
A team at JPL packed up three small Moon rovers, delivering them in February to the facility where they’ll be attached to a commercial lunar lander in preparation for launch. The rovers are part of a project called CADRE that could pave the way for potential future multirobot missions.. NASA/JPL-Caltech A trio of suitcase-size rovers and their base station have been carefully wrapped up and shipped off to join the lander that will deliver them to the Moon’s surface.
Three small NASA rovers that will explore the lunar surface as a team have been packed up and shipped from the agency’s Jet Propulsion Laboratory in Southern California, marking completion of the first leg of the robots’ journey to the Moon.
The rovers are part of a technology demonstration called CADRE (Cooperative Autonomous Distributed Robotic Exploration), which aims to show that a group of robots can collaborate to gather data without receiving direct commands from mission controllers on Earth. They’ll use their cameras and ground-penetrating radars to send back imagery of the lunar surface and subsurface while testing out the novel software that enables them to work together autonomously.
The CADRE rovers will launch to the Moon aboard IM-3, Intuitive Machines’ third lunar delivery, which has a mission window that extends into early 2026, as part of NASA’s CLPS (Commercial Lunar Payload Services) initiative. Once installed on Intuitive Machines’ Nova-C lander, they’ll head to the Reiner Gamma region on the western edge of the Moon’s near side, where the solar-powered, suitcase-size rovers will spend the daylight hours of a lunar day (the equivalent of about 14 days on Earth) carrying out experiments. The success of CADRE could pave the way for potential future missions with teams of autonomous robots supporting astronauts and spreading out to take simultaneous, distributed scientific measurements.
Members of a JPL team working on NASA’s CADRE technology demonstration use temporary red handles to move one of the project’s small Moon rovers to prepare it for transport to Intuitive Machines’ Houston facility, where it will be attached to the company’s third lunar lander. Construction of the CADRE hardware — along with a battery of rigorous tests to prove readiness for the journey through space — was completed in February 2024.
To get prepared for shipment to Intuitive Machines’ Houston facility, each rover was attached to its deployer system, which will lower it via tether from the lander onto the dusty lunar surface. Engineers flipped each rover-deployer pair over and attached it to an aluminum plate for safe transit. The rovers were then sealed in protective metal-frame enclosures that were fitted snuggly into metal shipping containers and loaded onto a truck. The hardware arrived safely on Sunday, Feb. 9.
“Our small team worked incredibly hard constructing these robots and putting them to the test, and we have been eagerly waiting for the moment where we finally see them on their way,” said Coleman Richdale, the team’s assembly, test, and launch operations lead at JPL. “We are all genuinely thrilled to be taking this next step in our journey to the Moon, and we can’t wait to see the lunar surface through CADRE’s eyes.”
The rovers, the base station, and a camera system that will monitor CADRE experiments on the Moon will be integrated with the lander — as will several other NASA payloads — in preparation for the launch of the IM-3 mission.
More About CADRE
A division of Caltech in Pasadena, California, JPL manages CADRE for the Game Changing Development program within NASA’s Space Technology Mission Directorate. The technology demonstration was selected under the agency’s Lunar Surface Innovation Initiative, which was established to expedite the development of technologies for sustained presence on the lunar surface. NASA’s Science Mission Directorate manages the CLPS initiative. The agency’s Glenn Research Center in Cleveland and its Ames Research Center in Silicon Valley, California, both supported the project. Motiv Space Systems designed and built key hardware elements at the company’s Pasadena facility. Clemson University in South Carolina contributed research in support of the project.
For more about CADRE, go to:
https://go.nasa.gov/cadre
News Media Contact
Melissa Pamer
Jet Propulsion Laboratory, Pasadena, Calif.
626-314-4928
melissa.pamer@jpl.nasa.gov
2025-018
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Last Updated Feb 11, 2025 Related Terms
CADRE (Cooperative Autonomous Distributed Robotic Exploration) Commercial Lunar Payload Services (CLPS) Earth's Moon Game Changing Development Program Jet Propulsion Laboratory Space Technology Mission Directorate Technology Technology Demonstration Explore More
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By NASA
5 min read
Preparations for Next Moonwalk Simulations Underway (and Underwater)
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NASA’s Curiosity Mars rover captured these drifting noctilucent, or twilight, clouds in a 16-minute recording on Jan. 17. (This looping clip has been speeded up about 480 times.) The white plumes falling out of the clouds are carbon dioxide ice that would evaporate closer to the Martian surface.NASA/JPL-Caltech/MSSS/SSI While the Martian clouds may look like the kind seen in Earth’s skies, they include frozen carbon dioxide, or dry ice.
Red-and-green-tinted clouds drift through the Martian sky in a new set of images captured by NASA’s Curiosity rover using its Mastcam — its main set of “eyes.” Taken over 16 minutes on Jan. 17 (the 4,426th Martian day, or sol, of Curiosity’s mission), the images show the latest observations of what are called noctilucent (Latin for “night shining”), or twilight clouds, tinged with color by scattering light from the setting Sun.
Sometimes these clouds even create a rainbow of colors, producing iridescent, or “mother-of-pearl” clouds. Too faint to be seen in daylight, they’re only visible when the clouds are especially high and evening has fallen.
Martian clouds are made of either water ice or, at higher altitudes and lower temperatures, carbon dioxide ice. (Mars’ atmosphere is more than 95% carbon dioxide.) The latter are the only kind of clouds observed at Mars producing iridescence, and they can be seen near the top of the new images at an altitude of around 37 to 50 miles (60 to 80 kilometers). They’re also visible as white plumes falling through the atmosphere, traveling as low as 31 miles (50 kilometers) above the surface before evaporating because of rising temperatures. Appearing briefly at the bottom of the images are water-ice clouds traveling in the opposite direction roughly 31 miles (50 kilometers) above the rover.
Dawn of Twilight Clouds
Twilight clouds were first seen on Mars by NASA’s Pathfinder mission in 1997; Curiosity didn’t spot them until 2019, when it acquired its first-ever images of iridescence in the clouds. This is the fourth Mars year the rover has observed the phenomenon, which occurs during early fall in the southern hemisphere.
Mark Lemmon, an atmospheric scientist with the Space Science Institute in Boulder, Colorado, led a paper summarizing Curiosity’s first two seasons of twilight cloud observations, which published late last year in Geophysical Research Letters. “I’ll always remember the first time I saw those iridescent clouds and was sure at first it was some color artifact,” he said. “Now it’s become so predictable that we can plan our shots in advance; the clouds show up at exactly the same time of year.”
Each sighting is an opportunity to learn more about the particle size and growth rate in Martian clouds. That, in turn, provides more information about the planet’s atmosphere.
Cloud Mystery
One big mystery is why twilight clouds made of carbon dioxide ice haven’t been spotted in other locations on Mars. Curiosity, which landed in 2012, is on Mount Sharp in Gale Crater, just south of the Martian equator. Pathfinder landed in Ares Vallis, north of the equator. NASA’s Perseverance rover, located in the northern hemisphere’s Jezero Crater, hasn’t seen any carbon dioxide ice twilight clouds since its 2021 landing. Lemmon and others suspect that certain regions of Mars may be predisposed to forming them.
A possible source of the clouds could be gravity waves, he said, which can cool the atmosphere: “Carbon dioxide was not expected to be condensing into ice here, so something is cooling it to the point that it could happen. But Martian gravity waves are not fully understood and we’re not entirely sure what is causing twilight clouds to form in one place but not another.”
Mastcam’s Partial View
The new twilight clouds appear framed in a partially open circle. That’s because they were taken using one of Mastcam’s two color cameras: the left 34 mm focal length Mastcam, which has a filter wheel that is stuck between positions. Curiosity’s team at NASA’s Jet Propulsion Laboratory in Southern California remains able to use both this camera and the higher-resolution right 100 mm focal length camera for color imaging.
The rover recently wrapped an investigation of a place called Gediz Vallis channel and is on its way to a new location that includes boxwork — fractures formed by groundwater that look like giant spiderwebs when viewed from space.
More recently, Curiosity visited an impact crater nicknamed “Rustic Canyon,” capturing it in images and studying the composition of rocks around it. The crater, 67 feet (20 meters) in diameter, is shallow and has lost much of its rim to erosion, indicating that it likely formed many millions of years ago. One reason Curiosity’s science team studies craters is because the cratering process can unearth long-buried materials that may have better preserved organic molecules than rocks exposed to radiation at the surface. These molecules provide a window into the ancient Martian environment and how it could have supported microbial life billions of years ago, if any ever formed on the Red Planet.
More About Curiosity
Curiosity was built by NASA’s Jet Propulsion Laboratory, which is managed by Caltech in Pasadena, California. JPL leads the mission on behalf of NASA’s Science Mission Directorate in Washington. Malin Space Science Systems in San Diego built and operates Mastcam.
For more about Curiosity, visit:
science.nasa.gov/mission/msl-curiosity
News Media Contacts
Andrew Good
Jet Propulsion Laboratory, Pasadena, Calif.
818-393-2433
andrew.c.good@jpl.nasa.gov
Karen Fox / Molly Wasser
NASA Headquarters, Washington
202-358-1600
karen.c.fox@nasa.gov / molly.l.wasser@nasa.gov
2025-017
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Last Updated Feb 11, 2025 Related Terms
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By NASA
NASA/Michael DeMocker The full moon rises over the Superdome and the city of New Orleans, Louisiana on Monday evening, January 13, 2025.
New Orleans is home to NASA’s Michoud Assembly Facility where several pieces of hardware for the SLS (Space Launch system) are being built. For more than half a century, NASA Michoud has been “America’s Rocket Factory,” the nation’s premiere site for manufacturing and assembly of large-scale space structures and systems.
See more photos from NASA Michoud.
Image credit: NASA/Michael DeMocker
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By NASA
NASA/Suni Williams Blue tentacle-like arms attached to an Astrobee free-flying robot grab onto a “capture cube” in this image from Feb. 4, 2025. The experimental grippers demonstrated autonomous detection and capture techniques that may be used to remove space debris and service satellites in low Earth orbit.
The Astrobee system was designed and built at NASA’s Ames Research Center in Silicon Valley for use inside the International Space Station. The system consists of three cube-shaped robots (named Bumble, Honey, and Queen), software, and a docking station used for recharging. The robots use electric fans as a propulsion system that allows them to fly freely through the microgravity environment of the station. Cameras and sensors help them to “see” and navigate their surroundings. The robots also carry a perching arm that allows them to grasp station handrails to conserve energy or to grab and hold items.
Image credit: NASA/Suni Williams
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