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By NASA
Researchers analyzing pulverized rock onboard NASA’s Curiosity rover have found the largest organic compounds on the Red Planet to date. The finding, published Monday in the Proceedings of the National Academy of Sciences, suggests prebiotic chemistry may have advanced further on Mars than previously observed.
Scientists probed an existing rock sample inside Curiosity’s Sample Analysis at Mars (SAM) mini-lab and found the molecules decane, undecane, and dodecane. These compounds, which are made up of 10, 11, and 12 carbons, respectively, are thought to be the fragments of fatty acids that were preserved in the sample. Fatty acids are among the organic molecules that on Earth are chemical building blocks of life.
Living things produce fatty acids to help form cell membranes and perform various other functions. But fatty acids also can be made without life, through chemical reactions triggered by various geological processes, including the interaction of water with minerals in hydrothermal vents.
While there’s no way to confirm the source of the molecules identified, finding them at all is exciting for Curiosity’s science team for a couple of reasons.
Curiosity scientists had previously discovered small, simple organic molecules on Mars, but finding these larger compounds provides the first evidence that organic chemistry advanced toward the kind of complexity required for an origin of life on Mars.
This graphic shows the long-chain organic molecules decane, undecane, and dodecane. These are the largest organic molecules discovered on Mars to date. They were detected in a drilled rock sample called “Cumberland” that was analyzed by the Sample Analysis at Mars lab inside the belly of NASA’s Curiosity rover. The rover, whose selfie is on the right side of the image, has been exploring Gale Crater since 2012. An image of the Cumberland drill hole is faintly visible in the background of the molecule chains. NASA/Dan Gallagher The new study also increases the chances that large organic molecules that can be made only in the presence of life, known as “biosignatures,” could be preserved on Mars, allaying concerns that such compounds get destroyed after tens of millions of years of exposure to intense radiation and oxidation.
This finding bodes well for plans to bring samples from Mars to Earth to analyze them with the most sophisticated instruments available here, the scientists say.
“Our study proves that, even today, by analyzing Mars samples we could detect chemical signatures of past life, if it ever existed on Mars,” said Caroline Freissinet, the lead study author and research scientist at the French National Centre for Scientific Research in the Laboratory for Atmospheres and Space Observations in Guyancourt, France
In 2015, Freissinet co-led a team that, in a first, conclusively identified Martian organic molecules in the same sample that was used for the current study. Nicknamed “Cumberland,” the sample has been analyzed many times with SAM using different techniques.
NASA’s Curiosity rover drilled into this rock target, “Cumberland,” during the 279th Martian day, or sol, of the rover’s work on Mars (May 19, 2013) and collected a powdered sample of material from the rock’s interior. Curiosity used the Mars Hand Lens Imager camera on the rover’s arm to capture this view of the hole in Cumberland on the same sol as the hole was drilled. The diameter of the hole is about 0.6 inches. The depth of the hole is about 2.6 inches. NASA/JPL-Caltech/MSSS Curiosity drilled the Cumberland sample in May 2013 from an area in Mars’ Gale Crater called “Yellowknife Bay.” Scientists were so intrigued by Yellowknife Bay, which looked like an ancient lakebed, they sent the rover there before heading in the opposite direction to its primary destination of Mount Sharp, which rises from the floor of the crater.
The detour was worth it: Cumberland turns out to be jam-packed with tantalizing chemical clues to Gale Crater’s 3.7-billion-year past. Scientists have previously found the sample to be rich in clay minerals, which form in water. It has abundant sulfur, which can help preserve organic molecules. Cumberland also has lots of nitrates, which on Earth are essential to the health of plants and animals, and methane made with a type of carbon that on Earth is associated with biological processes.
Perhaps most important, scientists determined that Yellowknife Bay was indeed the site of an ancient lake, providing an environment that could concentrate organic molecules and preserve them in fine-grained sedimentary rock called mudstone.
“There is evidence that liquid water existed in Gale Crater for millions of years and probably much longer, which means there was enough time for life-forming chemistry to happen in these crater-lake environments on Mars,” said Daniel Glavin, senior scientist for sample return at NASA’s Goddard Space Flight Center in Greenbelt, Maryland, and a study co-author.
The recent organic compounds discovery was a side effect of an unrelated experiment to probe Cumberland for signs of amino acids, which are the building blocks of proteins. After heating the sample twice in SAM’s oven and then measuring the mass of the molecules released, the team saw no evidence of amino acids. But they noticed that the sample released small amounts of decane, undecane, and dodecane.
Because these compounds could have broken off from larger molecules during heating, scientists worked backward to figure out what structures they may have come from. They hypothesized these molecules were remnants of the fatty acids undecanoic acid, dodecanoic acid, and tridecanoic acid, respectively.
The scientists tested their prediction in the lab, mixing undecanoic acid into a Mars-like clay and conducting a SAM-like experiment. After being heated, the undecanoic acid released decane, as predicted. The researchers then referenced experiments already published by other scientists to show that the undecane could have broken off from dodecanoic acid and dodecane from tridecanoic acid.
The authors found an additional intriguing detail in their study related to the number of carbon atoms that make up the presumed fatty acids in the sample. The backbone of each fatty acid is a long, straight chain of 11 to 13 carbons, depending on the molecule. Notably, non-biological processes typically make shorter fatty acids, with less than 12 carbons.
It’s possible that the Cumberland sample has longer-chain fatty acids, the scientists say, but SAM is not optimized to detect longer chains.
Scientists say that, ultimately, there’s a limit to how much they can infer from molecule-hunting instruments that can be sent to Mars. “We are ready to take the next big step and bring Mars samples home to our labs to settle the debate about life on Mars,” said Glavin.
This research was funded by NASA’s Mars Exploration Program. Curiosity’s Mars Science Laboratory mission is led by NASA’s Jet Propulsion Laboratory in Southern California; JPL is managed by Caltech for NASA. SAM (Sample Analysis at Mars) was built and tested at NASA’s Goddard Space Flight Center in Greenbelt, Maryland. CNES (the French Space Agency) funded and provided the gas chromatograph subsystem on SAM. Charles Malespin is SAM’s principal investigator.
By Lonnie Shekhtman
NASA’s Goddard Space Flight Center, Greenbelt, Md.
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By USH
Antarctica is shrouded in mystery, holding secrets from the past and serving as the site of ongoing covert operations. It's no surprise that numerous restricted zones exist to conceal the truth about what’s really happening there. The intrigue extends beyond the surface, hidden dangers lurk beneath the ice, particularly in the depths of Lake Vostok.
This hidden subglacial lake, sealed off from the world for 15 million years, holds secrets beyond imagination. Preserved in isolation, its ecosystem is unlike anything else on Earth.
When a Russian team drilled into Lake Vostok, they uncovered more than just ancient water. But something went wrong. Two scientists died under mysterious circumstances, and official reports contradict witness accounts. Military operations, classified research, and blurred satellite images suggest something is being hidden.
What are they trying to hide at the bottom of the world? Rumors speak of monstrous, spider-like entities, shape-shifting predators, and colossal, whale-like humanoids known as the "Ningen" a name that means "human" in Japanese.
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By NASA
2 min read
Preparations for Next Moonwalk Simulations Underway (and Underwater)
During the Apollo program, when NASA sent humans to the Moon, those missions took several days to reach the Moon. The fastest of these was Apollo 8, which took just under three days to go from Earth orbit to orbit around the Moon.
Now it’s possible to save some fuel by flying different kinds of trajectories to the Moon that are shaped in such a way to save fuel. And those trajectories can take more time, potentially weeks or months, to reach the Moon, depending on how you do it.
Mars is further away, about 50 percent further away from the Sun than Earth is. And reaching Mars generally takes somewhere between seven to ten months, flying a relatively direct route.
NASA’s Mars Reconnaissance Orbiter mission took about seven and a half months to reach Mars. And NASA’s MAVEN mission took about ten months to reach Mars.
Jupiter is about five times further away from the Sun than the Earth is. And so in order to make those missions practical, we have to find ways to reduce the fuel requirements. And the way we do that is by having the spacecraft do some flybys of Earth and or Venus to help shape the spacecraft’s trajectory and change the spacecraft’s speed without using fuel. And using that sort of approach, it takes between about five to six years to reach Jupiter.
So NASA’s Galileo mission, the first mission to Jupiter, took just a little over six years. And then NASA’s second mission to Jupiter, which was called Juno, took just under five years.
So to get to the Moon takes several days. To get to Mars takes seven to ten months. And getting to Jupiter takes between five and six years.
[END VIDEO TRANSCRIPT]
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