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Webb Detects Tiny Quartz Crystals in the Clouds of a Hot Gas Giant


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Webb Detects Tiny Quartz Crystals in the Clouds of a Hot Gas Giant

Researchers using NASA’s James Webb Space Telescope have detected evidence for quartz nanocrystals in the high-altitude clouds of WASP-17 b, a hot Jupiter exoplanet 1,300 light-years from Earth. The detection, which was uniquely possible with MIRI (Webb’s Mid-Infrared Instrument), marks the first time that silica (SiO2) particles have been spotted in an exoplanet atmosphere.

Illustration showing a portion of the disk of a cloudy planet set against the black background of space. About one-eighth of the planet is visible. It fills the lower right half of the frame, with the limb (the edge, or horizon) curving from the bottom left corner to the upper right corner. The planet is partially lit by a star that is off to the upper left, out of view. The planet is brightest along the limb (on the dayside), and grows dimmer toward the lower right corner (the nightside), becoming almost completely dark about halfway in. Wispy, light-tan-colored clouds are visible in the lit portion and there is a hazy blueish glow along the horizon. Several stars are scattered in the background.
This artist concept shows what the exoplanet WASP-17 b could look like.
Graphics: NASA, ESA, CSA, and R. Crawfor, d (STScI)Science: Nikole Lewis (Cornell University), David Grant (University of Bristol), Hannah Wakeford (University of Bristol) Crawford (STScI)

“We were thrilled!” said David Grant, a researcher at the University of Bristol in the UK and first author on a paper being published today in the Astrophysical Journal Letters. “We knew from Hubble observations that there must be aerosols—tiny particles making up clouds or haze—in WASP-17 b’s atmosphere, but we didn’t expect them to be made of quartz.”

Silicates (minerals rich in silicon and oxygen) make up the bulk of Earth and the Moon as well as other rocky objects in our solar system, and are extremely common across the galaxy. But the silicate grains previously detected in the atmospheres of exoplanets and brown dwarfs appear to be made of magnesium-rich silicates like olivine and pyroxene, not quartz alone – which is pure SiO2.


The result from this team, which also includes researchers from NASA’s Ames Research Center and NASA’s Goddard Space Flight Center, puts a new spin on our understanding of how exoplanet clouds form and evolve. “We fully expected to see magnesium silicates,” said co-author Hannah Wakeford, also from the University of Bristol. “But what we’re seeing instead are likely the building blocks of those, the tiny ‘seed’ particles needed to form the larger silicate grains we detect in cooler exoplanets and brown dwarfs.”

Detecting Subtle Variations


With a volume more than seven times that of Jupiter and a mass less than one-half Jupiter, WASP-17 b is one of the largest and puffiest known exoplanets. This, along with its short orbital period of just 3.7 Earth-days, makes the planet ideal for transmission spectroscopy : a technique that involves measuring the filtering and scattering effects of a planet’s atmosphere on starlight.


Webb observed the WASP-17 system for nearly 10 hours, collecting more than 1,275 brightness measurements of 5- to 12-micron mid-infrared light as the planet crossed its star. By subtracting the brightness of individual wavelengths of light that reached the telescope when the planet was in front of the star from those of the star on its own, the team was able to calculate the amount of each wavelength blocked by the planet’s atmosphere.


What emerged was an unexpected “bump” at 8.6 microns, a feature that would not be expected if the clouds were made of magnesium silicates or other possible high temperature aerosols like aluminum oxide, but which makes perfect sense if they are made of quartz.

alt="Graphic titled “Hot Gas Giant Exoplanet WASP-17 b Composition of Cloud Particles, MIRI Low-Resolution Time-Series Spectroscopy” showing 28 data points plotted as white circles with vertical error bars on a graph of amount of light blocked in percent on the y-axis versus wavelength of light in microns on the x-axis. The y-axis ranges from 1.45 to 1.65 percent. The x-axis ranges from 5 to 12 microns. A jagged purple line is labeled “Model spectrum based on Webb, Hubble, and Spitzer data.” One broad, prominent peak visible in the data and model is highlighted with a vertical green band labeled “Light blocked by quartz (S I O 2) crystals.” The peak is centered at about 8.6 microns and 1.59 percent. Running across the green band below the purple peak, is a jagged dashed yellow line labeled “What the spectrum would look like with no quartz clouds.” This line slopes down to the right. In the background is an illustration of a planet with wispy clouds and a hazy blueish glow along the horizon."
A transmission spectrum of the hot gas giant exoplanet WASP-17 b captured by Webb’s Mid-Infrared Instrument (MIRI) on March 12-13, 2023, reveals the first evidence for quartz (crystalline silica, SiO2) in the clouds of an exoplanet. The spectrum was made by measuring the change in brightness of 28 wavelength-bands of mid-infrared light as the planet transited the star. Webb observed the WASP-17 system using MIRI’s low-resolution spectrograph for nearly 10 hours, collecting more than 1,275 measurements before, during, and after the transit. For each wavelength, the amount of light blocked by the planet’s atmosphere (white circles) was calculated by subtracting the amount that made it through the atmosphere from the amount originally emitted by the star. The solid purple line is a best-fit model to the Webb (MIRI), Hubble, and Spitzer data. (The Hubble and Spitzer data cover wavelengths from 0.34 to 4.5 microns and are not shown on the graph.) The spectrum shows a clear feature around 8.6 microns, which astronomers think is caused by silica particles absorbing some of the starlight passing through the atmosphere. The dashed yellow line shows what that part of the transmission spectrum would look like if the clouds in WASP-17 b’s atmosphere did not contain SiO2. This marks the first time that SiO2 has been identified in an exoplanet, and the first time any specific cloud species has been identified in a transiting exoplanet.
Graphics: NASA, ESA, CSA, and R. Crawfor, d (STScI)Science: Nikole Lewis (Cornell University), David Grant (University of Bristol), Hannah Wakeford (University of Bristol) Crawford (STScI)

Download full resolution images for this article from the Space Telescope Science Institute (STScI)

Crystals, Clouds, and Winds


While these crystals are probably similar in shape to the pointy hexagonal prisms found in geodes and gem shops on Earth, each one is only about 10 nanometers across—one-millionth of one centimeter.


“Hubble data actually played a key role in constraining the size of these particles,” explained co-author Nikole Lewis of Cornell University, who leads the Webb Guaranteed Time Observation (GTO) program designed to help build a three-dimensional view of a hot Jupiter atmosphere. “We know there is silica from Webb’s MIRI data alone, but we needed the visible and near-infrared observations from Hubble for context, to figure out how large the crystals are.”


Unlike mineral particles found in clouds on Earth, the quartz crystals detected in the clouds of WASP-17 b are not swept up from a rocky surface. Instead, they originate in the atmosphere itself. “WASP-17 b is extremely hot—around 1,500 degrees Celsius (2,700°F)—and the pressure where they form high in the atmosphere is only about one-thousandth of what we experience on Earth’s surface,” explained Grant. “In these conditions, solid crystals can form directly from gas, without going through a liquid phase first.”


Understanding what the clouds are made of is crucial for understanding the planet as a whole. Hot Jupiters like WASP-17 b are made primarily of hydrogen and helium, with small amounts of other gases like water vapor (H2O) and carbon dioxide (CO2). “If we only consider the oxygen that is in these gases, and neglect to include all of the oxygen locked up in minerals like quartz (SiO2), we will significantly underestimate the total abundance,” explained Wakeford. “These beautiful silica crystals tell us about the inventory of different materials and how they all come together to shape the environment of this planet.”


Exactly how much quartz there is, and how pervasive the clouds are, is hard to determine. “The clouds are likely present along the day/night transition (the terminator), which is the region that our observations probe,” said Grant. Given that the planet is tidally locked with a very hot day side and cooler night side, it is likely that the clouds circulate around the planet, but vaporize when they reach the hotter day side. “The winds could be moving these tiny glassy particles around at thousands of miles per hour.”


WASP-17 b is one of three planets targeted by the JWST-Telescope Scientist Team’s Deep Reconnaissance of Exoplanet Atmospheres using Multi-instrument Spectroscopy (DREAMS) investigations, which are designed to gather a comprehensive set of observations of one representative from each key class of exoplanets: a hot Jupiter, a warm Neptune, and a temperate rocky planet. The MIRI observations of hot Jupiter WASP-17 b were made as part of GTO program 1353.


The James Webb Space Telescope is the world’s premier space science observatory. Webb is solving mysteries in our solar system, looking beyond to distant worlds around other stars, and probing the mysterious structures and origins of our universe and our place in it. Webb is an international program led by NASA with its partners, ESA (European Space Agency) and the Canadian Space Agency.

Media Contacts:

Laura Betz
NASA’s Goddard Space Flight Center, Greenbelt, Md.
laura.e.betz@nasa.gov

Christine Pulliam
Space Telescope Science Institute, Baltimore, Md.
cpulliam@stsci.edu

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      Last Updated Oct 30, 2024 Editor Marty McCoy Contact Laura Betz laura.e.betz@nasa.gov Related Terms
      Astrophysics Galaxies Galaxies, Stars, & Black Holes Research Goddard Space Flight Center Hubble Space Telescope James Webb Space Telescope (JWST) Science & Research Spiral Galaxies The Universe View the full article
    • By NASA
      3 min read
      Buckle Up: NASA-Funded Study Explores Turbulence in Molecular Clouds
      This image shows the distribution of density in a simulation of a turbulent molecular cloud. NASA/E. Scannapieco et al (2024) On an airplane, motions of the air on both small and large scales contribute to turbulence, which may result in a bumpy flight. Turbulence on a much larger scale is important to how stars form in giant molecular clouds that permeate the Milky Way.
      In a new NASA-funded study in the journal Science Advances, scientists created simulations to explore how turbulence interacts with the density of the cloud. Lumps, or pockets of density, are the places where new stars will be born. Our Sun, for example, formed 4.6 billion years ago in a lumpy portion of a cloud that collapsed.
      “We know that the main process that determines when and how quickly stars are made is turbulence, because it gives rise to the structures that create stars,” said Evan Scannapieco, professor of astrophysics at Arizona State University and lead author of the study. “Our study uncovers how those structures are formed.”
      Giant molecular clouds are full of random, turbulent motions, which are caused by gravity, stirring by the galactic arms and winds, jets, and explosions from young stars. This turbulence is so strong that it creates shocks that drive the density changes in the cloud.
      The simulations used dots called tracer particles to traverse a molecular cloud and travel along with the material. As the particles travel, they record the density of the part of the cloud they encounter, building up a history of how pockets of density change over time. The researchers, who also included Liubin Pan from Sun Yat Sen University in China, Marcus Brüggen from the University of Hamburg in Germany, and Ed Buie II from Vassar College in Poughkeepsie, New York, simulated eight scenarios, each with a different set of realistic cloud properties.  
      This animation shows the distribution of density in a simulation of a turbulent molecular cloud. The colors represent density, with dark blue indicating the least dense regions and red indicating the densest regions. Credit: NASA/E. Scannapieco et al (2024) The team found that the speeding up and slowing down of shocks plays an essential role in the path of the particles.  Shocks slow down as they go into high-density gas and speed up as they go into low-density gas. This is akin to how an ocean wave strengthens when it hits shallow water by the shore.   
      When a particle hits a shock, the area around it becomes more dense. But because shocks slow down in dense regions, once lumps become dense enough, the turbulent motions can’t make them any denser.  These lumpiest high-density regions are where stars are most likely to form.
      While other studies have explored molecular cloud density structures, this simulation allows scientists to see how those structures form over time. This informs scientists’ understanding of how and where stars are likely to be born.
      “Now we can understand better why those structures look the way they do because we’re able to track their histories,” said Scannapieco.
      This image shows part of a simulation of a molecular cloud. The colors represent density, with dark blue indicating the least dense regions and red indicating the densest regions. Tracer particles, represented by black dots, traverse the simulated cloud. By examining how they interact with shocks and pockets of density, scientists can better understand the structures in molecular clouds that lead to star formation. NASA/E. Scannapieco et al (2024) NASA’s James Webb Space Telescope is exploring the structure of molecular clouds. It is also exploring the chemistry of molecular clouds, which depends on the history of the gas modeled in the simulations. New measurements like these will inform our understanding of star formation.
      View the full article
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