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The safety and performance of hazardous propellant systems is a main focus at White Sands Test Facility. Our workforce conducts laboratory micro-analysis to full-scale field explosion tests. With the expertise we have developed, we provide training to the aerospace industry in the safe handling of various propellants.
We also provide analysis of systems and operational safety, propellant spec analysis, personal protective equipment assessment, and detection technologies for both industrial and flight applications for our propulsion testing team and end users in aerospace and industry.

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      This article is from the 2024 Technical Update.

      The NESC evaluated material compatibility of some common aerospace metals in monomethylhydrazine (MMH) and nitrogen tetroxide (MON-3). Previous work had identified a lack of quantitative compatibility data for nickel alloy 718, 300 series stainless steel, and titanium Ti-6Al-4V in MMH and MON-3 to support the use of zero-failure-tolerant, thin-walled pressure barriers in these propellants. Static (i.e., not flowing) general corrosion and electrochemistry testing was conducted, evaluating varied processing forms and heat treatment of the metals, water content of propellant, and exposure duration. Corrosion-rate data for all tested product forms, fluids, and durations were on the order of 1 x 10–6 inch per year rather than the previously documented “less than 1 x 10–3 inch per year”. The majority of the corrosion products were seen in the first 20 days of exposure, with an overall corrosion rate decreasing with time due to the increased divisor (time). It is therefore recommended that corrosion testing be performed at multiple short-term durations to inform the need for longer-duration testing.

      Background
      Nickel alloy 718, 300 series stainless steel, and Ti-6Al-4V are commonly used in storable propulsion systems (i.e., MMH/MON-3), but a concern was raised regarding what quantitative compatibility data were available for proposed zero-failure-tolerant, thin-walled (~0.005 to 0.010 inch thickness) pressure barrier designs. A literature search found that limited and conflicting data were available for commonly used aerospace metals in MMH and MON-3. For example, corrosion behavior was listed qualitatively (e.g., “A” rating), data on materials and fluids tested were imprecise, fluids were identified as contaminated without describing how they were contaminated, no compatibility data were found on relevant geometry specimens (i.e., very thin-walled or convoluted), and limited data were available to quantify differences between tested materials and flight components. When corrosion data were quantified, documented sensitivity was “1 x 10–3 inch per year or less”, which is insufficient for assessing long-duration, thin-walled, flight-weight applications.
      Discussion
      General corrosion testing was performed with a static/non-flowing configuration based on NASA-STD-6001, Test 15 [1]. Design of experiments methods were used to develop a test matrix varying material, propellant, propellant water content, and tested duration. Materials tested were nickel alloy 718 (solution annealed sheet, aged sheet, aged/welded sheet, and hydroformed bellows), 300 series stainless steel (low carbon sheet, titanium stabilized sheet, and hydroformed bellows), and Ti 6Al-4V sheet. Samples were tested in sealed test tubes in MMH and MON-3 with water content ranging from as-received (“dry”) up to specification allowable limits [2,3]. Tested durations ranged from 20 to 365 days. Measurements included inductively coupled plasma mass spectrometry (ICPMS) to identify corrosion products and their concentrations in test fluid, gravimetric (i.e., scale) measurements pre- and post-exposure, and visual inspection. Bimetallic pairs (titanium stabilized 300 series stainless steel: Ti 6Al-4V and nickel alloy 718: Ti 6Al-4V) were tested for up to 65 days in both MMH and MON-3. The test setup incorporated important features of the test standard (e.g., electrode spacing and finish) and adapted the configuration for MMH/MON-3 operation. Measurements included potential difference and current flow between samples. Figure 1 shows images of the general corrosion and bimetallic pair test setups.
      Test Results
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      Recommendations
      It is recommended that corrosion testing be performed at multiple shortterm durations to inform the need for longer-duration testing.

      References
      NASA-STD-6001 Flammability, Odor, Offgassing, and Compatibility Requirements
      and Test Procedures for Materials In Environments that Support Combustion MIL-PRF-27404 Performance Specification: Propellant, Monomethylhydrazine MIL-PRF-26539 Performance Specification: Propellants, Dinitrogen Tetroxide WSTF Test 15 Report 12-45708 and WSTF Test 15 Report 13-46207 View the full article
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      757-751-2034  davidlee.t.meade@nasa.gov
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      Last Updated Nov 12, 2024 EditorRob GarnerContactRob Garnerrob.garner@nasa.govLocationGoddard Space Flight Center Related Terms
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      -end-
      Tiernan Doyle
      Headquarters, Washington
      202-358-1600
      tiernan.doyle@nasa.gov
      Rachel Hoover
      Ames Research Center, Silicon Valley, Calif.
      650-604-4789
      rachel.hoover@nasa.gov
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      Last Updated Oct 10, 2024 LocationNASA Headquarters Related Terms
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